Poster of our laboratory
Interactions between hydrated cerium(III) cations and carboxylates in aqueous solution: Anomalously strong complex formation with diglycolate suggesting a chelate effect
Interactions between hydrated Ce3+ and various carboxylates are of fundamental interest. Anomalously strong interactions with Ce3+ occur when adding diglycolic acid (DGA) into a Ce3+ aqueous solution, unlike various other carboxylic acids. The complex formation constants of Ce3+ with these acids are evaluated via absorption and emission spectra. Hydrated Ce3+ emits fluorescence with unity quantum yield; however, adding various carboxylates statically quenches the fluorescence when Ce3+‒carboxylate complexes form, because the fluorescence lifetime is constant irrespective of the carboxylate concentration. In the observed static quenching, the complex formation constants obtained from the absorption and emission spectra (Kabs and Kem) agree well. The binding Ce3+ by the conjugate Lewis bases, i.e., carboxylates is approximately inversely proportional to the pH. Adding DGA into the system also statically quenches the fluorescence, but far more efficiently, even in a much weaker solution. We rigorously deduce Kabs and Kem of Ce3+ with DGA without any approximation using comparable concentrations. Careful fittings provide equivalent Kem and Kabs values, and varying the pH and ionic strength confirms this equivalence is an inherent property of the Ce3+-DGA system. Lewis acid–base theory cannot explain DGA binds Ce3+ ~1000 times more strongly than the other carboxylates. This anomalously strong binding may be due to a chelate effect caused by the DGA’s central oxygen atom, which forms a five-membered ring with the conjugate Lewis bases of DGA; double chelate rings can also form, while bis-deprotonated DGA binds Ce3+, facilitated by the central oxygen. Therefore, DGA enables efficient quenching through the chelate effect when it binds Ce3+.
Advancing the a posteriori quest for deep-blue phosphorescence: Quantifying excitation-induced metal-to-ligand charge transfer as a guiding indicator
To advance the a posteriori quest for deep-blue phosphorescence, we quantify the degree of metal-to-ligand charge trans-fer (MLCT) upon excitation using density functional theory calculations. We also comprehensively determine how the MLCT nature of a state is correlated with the wavelength of potential phosphorescence through comparing the results of two typical ligand structures, i.e., 2-phenylpyridine and 1-phenyl-3-methylimidazolin-2-ylidene, with those of their derivatives. The MLCT nature can be defined as the difference in the electron density over the central metal ion that contributes to the highest occupied and lowest unoccupied molecular orbitals (HOMO and LUMO, respectively). This study focuses on how the MLCT nature can be characterized upon excitation depending on the admixtures of molecular orbitals and how a stronger MLCT nature is preferable for efficient phosphorescence, while the MLCT nature exhibits a trade-off relationship with the wavelengths of phosphorescence in the blue region. Moreover, we elucidate how iridium(III) complexes are suitable for efficient phosphorescence and discuss a conceptual grand design for transition-metal complexes with deep-blue phosphorescence using the ligand field theory. We examine why strong MLCT nature upon excitation does not necessarily ensure highly efficient phosphorescence, taking into account possible relative energy gaps between the singlet MLCT, triplet locally excited, and d‒d transition states in a transition-metal complex formed after excitation. Nevertheless, the initial MLCT serves as a necessary condition that induces corollary energy-state configurations as well as decay from the excited states. Therefore, quantifying the nature of that MLCT, which is the first process upon excitation, with the possible wavelength of phosphorescence, is a useful parameter for a conceptual grand design for candidate complexes that can efficiently emit deep-blue phosphorescence. This reverse method of analyzing candidate complexes before experimentally formulating and studying them can accelerate the a posteriori quest for deep-blue-emitting materials.
Novel discovery in molecular alignment and orientation of an organic semiconductor molecule while temperature changes.
We observe potential randomization and constraint of molecular alignment and orientation in an organic semiconductor molecule with increasing temperature up to the phase-transition temperature. Variable-angle spectroscopic ellipsometry and second-harmonic generation (SHG) are used to study changes in the molecular alignment in vapor-deposited organic thin films as samples are heated and cooled in a cycle from room temperature to the phase-transition temperature. The films consist of sterically bulky and cross-shaped molecules, 2-cyano-9,10-di(2-naphthyl)anthracene (CADN), and the anisotropy of its two moieties is probed. Anisotropic molecular alignment with respect to the surface normal in as-deposited amorphous films changes with the film thickness, which increases slightly with increasing substrate temperature. Moreover, the long axis of the anthracene moiety changes significantly with respect to the surface normal from the magic angle to isotropic alignment, showing monotonically decreasing anisotropy. Interestingly, the anisotropy of the long axis of the anthracene moiety disappears before the phase-transition temperature. In contrast, the short axis of the anthracene moiety exhibits a notable characteristic change in the temperature dependent alignment during the heating process; although the anisotropy initially decreases, it significantly increases as the temperature approaches the phase transition. At a certain temperature during heating, the film thickness shows a discontinuous jump, similar to a first phase transition, while the anisotropic molecular alignment completely disappears. During the cooling process after the phase transition, however, properties of the films are irreversibly changed, and anisotropic molecular alignment is no longer observed; thus, the samples become completely isotropic.
Significantly new approach to analyze photoluminescence properties: Electronic ground state analysis of phosphors
This study theoretically models the electronic states of a series of Eu(II)-doped alkali-earth sulfide phosphors using density functional theory calculations to investigate characterize their photoluminescence properties in terms of quantum efficiency and its thermal decay tendency. We believe that our study makes a significant contribution to the literature because we propose a practical and effective parameter that explains the rankings of quantum yield and its temperature dependence in three of the four phosphor systems, which follow the Dorenbos thermal quenching model. Specifically, this parameter is a ratio of probability amplitudes that reflects the degree to which electrons are localized. Further, we believe that this paper will be of interest to the readership of your journal because our ab initio calculations help to identify the physical reasons underlying the thermal quenching of photoluminescent materials. The parameter presented herein will potentially help other researchers theoretically probe the physics underlying the photoluminescence of phosphors and predict their thermal quenching properties.
Review of in-plane switching technology as summary of an epoch-making technology in LCDs
We present an overview of in-plane switching (IPS) technologies in terms of historical background, nascent fundamental findings and developments, breakthroughs in addressing display performance issues, and the evolution of materials and device structures. The focus is on how IPS technology has been developed along with changes in the required display characteristics as the target display products continue to evolve. In addition, innovative manufacturing processes, such as photo-alignment technology, have led to the further evolution of IPS technology. Starting with the fundamental frameworks at an early stage, the evolution and development of IPS technology are described as extensively as possible.